H├╢rmander operators are a class of linear second order partial differential operators with nonnegative characteristic form and smooth coefficients, which are usually degenerate elliptic-parabolic, but nevertheless hypoelliptic, that is highly regularizing. The study of these operators began with the 1967 fundamental paper by Lars H├╢rmander and is intimately connected to the geometry of vector fields.Motivations for the study of H├╢rmander operators come for instance from Kolmogorov-Fokker-Planck equations arising from modeling physical systems governed by stochastic equations and the geometric theory of several complex variables. The aim of this book is to give a systematic exposition of a relevant part of the theory of H├╢rmander operators and vector fields, together with the necessary background and prerequisites.The book is intended for self-study, or as a reference book, and can be useful to both younger and senior researchers, already working in this area or aiming to approach it.